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Abstract:

Examination of thermal decomposition of street samples of cocaine and methamphetamine shows that typical products detected in previous studies are accompanied by a wide palette of simple volatile compounds easily detectable by spectral techniques. These molecules increase smoke toxicity and their spectral detection can be potentially used for identification of drug samples by well-controlled laboratory thermolysis in temperature progression. In our study, street samples of cocaine and methamphetamine have been thermolyzed under vacuum over the temperature range of 350-650 °C. The volatile products (CO, HCN, CH₄, C₂H₄, etc.) have been monitored by high-resolution Fourier-transform infrared (FTIR) spectrometry in this temperature range. The decomposition mechanism has been additionally examined theoretically by quantum-chemical calculations for the highest temperature achieved experimentally in our study and beyond. Prior to analysis, the street samples have also been characterized by FTIR, Raman spectroscopy, energy-dispersive X-ray spectroscopy, and melting point determination.

Abstract:

Eruptive column models are powerful tools for investigating the transport of volcanic gas and ash, reconstructing past explosive eruptions, and simulating future hazards. However, the evaluation of these models is challenging as it requires independent estimates of the main model inputs (e.g. mass eruption rate) and outputs (e.g. column height). There exists no database of independently estimated eruption source parameters (ESPs) that is extensive, standardized, maintained, and consensus-based. This paper introduces the Independent Volcanic Eruption Source Parameter Archive (IVESPA, ivespa.co.uk), a community effort endorsed by the International Association of Volcanology and Chemistry of the Earth's Interior (IAVCEI) Commission on Tephra Hazard Modelling. We compiled data for 134 explosive eruptive events, spanning the 1902-2016 period, with independent estimates of: i) total erupted mass of fall deposits; ii) duration; iii) eruption column height; and iv) atmospheric conditions. Crucially, we distinguish plume top versus umbrella spreading height, and the height of ash versus sulphur dioxide injection. All parameter values provided have been vetted independently by at least two experts. Uncertainties are quantified systematically, including flags to describe the degree of interpretation of the literature required for each estimate. IVESPA also includes a range of additional parameters such as total grain size distribution, eruption style, morphology of the plume (weak versus strong), and mass contribution from pyroclastic density currents, where available. We discuss the future developments and potential applications of IVESPA and make recommendations for reporting ESPs to maximize their usability across different applications. IVESPA covers an unprecedented range of ESPs and can therefore be used to evaluate and develop eruptive column models across a wide range of conditions using a standardized dataset.

Abstract:

<p>Raikoke, a remote volcano in the Kuril Islands, erupted on the 21<sup>st</sup> June 2019. The eruption injected significant quantities of SO<sub>2</sub> into the atmosphere along with volcanic ash. These plumes have been studied with tools developed for the Infrared Atmospheric Sounding Interferometer (IASI) by the Earth Observation Data Group (EODG) at the University of Oxford. IASI is a hyperspectral sensor onboard of three meteorological satellites (Metop A, B and C). Each instrument obtains near global coverage twice a day and has a spectral range which includes sensitivity to both SO<sub>2</sub> and ash: making them useful for studying the Raikoke plumes. A fast linear SO<sub>2</sub> retrieval was first applied to flag pixels with elevated amounts of SO<sub>2</sub>. With this tool it was possible to follow the Raikoke plume as it circulated the northern hemisphere above 30 degrees, with parts of the plume still visible around 2 months after the eruption took place. Next an iterative SO<sub>2</sub> retrieval was used to quantify the amount and height of the SO<sub>2</sub> in each pixel. In the first few days after the eruption took place, very high column amounts are recorded, in some cases exceeding 600 DU. Using this retrieval, a preliminary estimate of 1.6 Tg was obtained for the total amount of SO<sub>2 </sub>emitted (measured on the 23<sup>rd</sup> of June). Height information from this technique shows that there were probably multiple injection heights during the eruption and that SO<sub>2</sub> was emitted into both the troposphere and stratosphere. The tropospheric plume remains visible for just a few days after the eruption, while the stratospheric portion of the plume persists for several weeks.</p>