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Abstract:

Mildly irradiated mini-Neptunes have densities potentially consistent with them hosting substantial liquid-water oceans ("Hycean" planets). The presence of CO2 and simultaneous absence of ammonia (NH3) in their atmospheres has been proposed as a fingerprint of such worlds. JWST observations of K2-18b, the archetypal Hycean, have found the presence of CO2 and the depletion of NH3 to 4 μm region, where CO2 and CO features dominate: magma ocean models suggest a systematically lower CO2/CO ratio than estimated from free-chemistry retrieval, indicating that deeper observations of this spectral region may be able to distinguish between oceans of liquid water and magma on mini-Neptunes

Abstract:

Abstract Compositional convection is atmospheric mixing driven by density variations caused by compositional gradients. Previous studies have suggested that compositional gradients of atmospheric trace species within planetary atmospheres can impact convection and the final atmospheric temperature profile. In this work, we employ 3D convection-resolving simulations using Cloud Model 1 (CM1) to gain a fundamental understanding of how compositional variation influences convection and the final atmospheric state of exoplanet atmospheres. We perform 3D initial value problem simulations of noncondensing compositional convection for Earth-air, H 2 , and CO 2 atmospheres. Conventionally, atmospheric convection is assumed to mix the atmosphere to a final, marginally stable state defined by a unique temperature profile. However, when there is compositional variation within an atmosphere, a continuous family of stable end states is possible, differing in the final state composition profile. Our CM1 simulations are used to determine which of the family of possible compositional end states is selected. Leveraging the results from our CM1 simulations, we develop a dry convective adjustment scheme for use in general circulation models (GCMs). This scheme relies on an energy analysis to determine the final adjusted atmospheric state. Our convection scheme produces results that agree with our CM1 simulations and can easily be implemented in GCMs to improve modeling of compositional convection in exoplanet atmospheres.