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Abstract:

AbstractThe dimension is a leading parameter in customization of unique optoelectronic properties of halide perovskite, while it is still challenging to achieve dimension control beyond the well‐developed composition regulation‐based strategy considering their intrinsic feature of ionic crystal. In this paper, ligands‐directed confinement effect is emphasized in rendering the reduced‐dimensional engineering of halide perovskite, and quasi‐2D (OAm)2CsPb2Br7 (n = 2) nanosheets are obtained by introducing a large amount of metal ions. As a representation, with Mg2+ participation, the initial adsorption of organic ligands (i.e., OA and OAm) to inorganic components (i.e., [PbBr6]4−) is promoted, conferring a ligands‐directed surface reconstruction to form the lamellar structure composed of alternate organic and inorganic layers. Namely, the inorganic–organic lamellar ensemble will play as a soft template, which effectively restricts the growth of [PbBr6]4− in the c‐axis direction even after the Cs‐OA injection, thus producing the anisotropic layered perovskite of (OAm)2CsPb2Br7 from CsPbBr3 scenario. Notably, such reduced‐dimensional engineering enables a remarkable luminescence tailoring, of which the deep blue emission centered at 439 nm is achieved. In addition, benefiting from such universal strategy, the luminescence is also dependent on the species of introduced metal ions (e.g., Ca2+, Co2+, Sr2+, and Mn2+).

Abstract:

Having captivated the research community with simple fabrication processes and staggering device efficiencies, perovskite-based optoelectronics are already on the way to commercialization. However, one potential obstacle to this commercialization is the almost exclusive use of toxic, highly coordinating, high boiling point solvents to make perovskite precursor inks. Herein, we demonstrate that nonpolar organic solvents, such as toluene, can be combined with butylamine to form an effective solvent for alkylammonium-based perovskites. Beyond providing broader solvent choice, our finding opens the possibility of blending perovskite inks with a wide range of previously incompatible materials, such as organic molecules, polymers, nanocrystals, and structure-directing agents. As a demonstration, using this solvent, we blend the perovskite ink with 6,6-phenyl-C-61-butyric acid methyl ester and show improved perovskite crystallization and device efficiencies. This processing route may enable a myriad of new possibilities for tuning the active layers in efficient photovoltaics, light-emitting diodes, and other semiconductor devices.