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Abstract:

The characterisation of exoplanetary atmospheres has entered a new era with the advent of the James Webb Space Telescope (JWST), which enables the detection of molecular species in the atmospheres of both gas giants and smaller, potentially rocky planets. This thesis focuses on the development and application of atmospheric retrieval methods to interpret transmission spectra from JWST observations, with particular attention to assumptions in atmospheric models and their impact on the resulting inferences. The first part of this thesis examines how specific modelling choices can influence atmospheric retrievals. I investigate the role of planetary rotation in modifying effective gravity and demonstrate that the inclusion of centrifugal forces can alter retrieved atmospheric properties, particularly for low-density, fast-rotating planets that are common targets for transmission spectroscopy. I also explore the implementation of Centered Log-Ratio (CLR) priors for atmospheric composition, a method designed to better represent the statistical priors of gas abundances in retrievals. This is particularly relevant for smaller exoplanets, where the dominant atmospheric constituents are often unknown and conventional priors can lead to biased results. The second part of the thesis presents retrievals on JWST Early Release Science observations for the hot Saturn WASP-39 b. I apply the NEMESISPY retrieval framework to transmission spectra obtained using multiple JWST instruments using both free retrieval and equilibrium chemistry approaches. These analyses highlight the strengths and limitations of each method and illustrate how the choice of parameterisation and integration of chemical equilibrium codes can impact inferences about the atmospheric conditions on a planet. The final chapters focus on a 1.5 R_earth exoplanet L 98-59 d. Using a JWST transmission spectrum obtained with the NIRSpec G395H instrument, I perform a range of retrievals to test what can be inferred about its atmosphere. My analysis suggests the potential presence of a high mean molecular weight atmosphere dominated by the sulfur-bearing gases H2S and SO2. While these initial results are tentative, I outline an observational strategy targeting additional transits using complementary wavelengths to constrain its composition more robustly. Taken together, the work presented in this thesis examines assumptions in the technique of atmospheric retrieval and demonstrates its application to a diverse set of exoplanets. It shows how careful treatment of model assumptions and priors can improve the robustness of interpretations and enhance the scientific return from JWST observations. As the focus of exoplanet science shifts toward smaller and cooler planets, these tools and approaches will be essential for addressing fundamental questions about atmospheric diversity and the potential for habitability beyond our Solar System

Abstract:

ESA's Jupiter Icy Moons Explorer (JUICE) will provide a detailed investigation of the Jovian system in the 2030s, combining a suite of state-of-the-art instruments with an orbital tour tailored to maximise observing opportunities. We review the Jupiter science enabled by the JUICE mission, building on the legacy of discoveries from the Galileo, Cassini, and Juno missions, alongside ground- and space-based observatories. We focus on remote sensing of the climate, meteorology, and chemistry of the atmosphere and auroras from the cloud-forming weather layer, through the upper troposphere, into the stratosphere and ionosphere. The Jupiter orbital tour provides a wealth of opportunities for atmospheric and auroral science: global perspectives with its near-equatorial and inclined phases, sampling all phase angles from dayside to nightside, and investigating phenomena evolving on timescales from minutes to months. The remote sensing payload spans far-UV spectroscopy (50-210 nm), visible imaging (340-1080 nm), visible/near-infrared spectroscopy (0.49-5.56 μm), and sub-millimetre sounding (near 530-625 GHz and 1067-1275 GHz). This is coupled to radio, stellar, and solar occultation opportunities to explore the atmosphere at high vertical resolution; and radio and plasma wave measurements of electric discharges in the Jovian atmosphere and auroras. Cross-disciplinary scientific investigations enable JUICE to explore coupling processes in giant planet atmospheres, to show how the atmosphere is connected to (i) the deep circulation and composition of the hydrogen-dominated interior; and (ii) to the currents and charged particle environments of the external magnetosphere. JUICE will provide a comprehensive characterisation of the atmosphere and auroras of this archetypal giant planet.

Abstract:

We present an atmospheric analysis of LTT 9779 b, a rare planet situated in the hot-Neptune desert, that has been observed with Hubble Space Telescope (HST)/WFC3 with G102 and G141. The combined transmission spectrum, which covers 0.8–1.6 μm, shows a gradual increase in transit depth with wavelength. Our preferred atmospheric model shows evidence for H2O, CO2, and FeH with a significance of 3.1σ, 2.4σ, and 2.1σ, respectively. In an attempt to constrain the rate of atmospheric escape for this planet, we search for the 1.083 μm helium line in the G102 data but find no evidence of excess absorption that would indicate an escaping atmosphere using this tracer. We refine the orbital ephemerides of LTT 9779 b using our HST data and observations from TESS, searching for evidence of orbital decay or apsidal precession, which are not found. The phase-curve observation of LTT 9779 b with JWST NIRISS should provide deeper insights into the atmosphere of this planet and the expected atmospheric escape might be detected with further observations concentrated on other tracers such as Lyα