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Abstract:

We report the first detection of stratospheric propadiene (CH₂CCH₂) and propene (C₃H₆) at Jupiter’s mid-to-high northern latitudes using IRTF-TEXES measurements recorded on March 5-6, 2025. Using radiative transfer software to quantitatively test for the presence of propadiene and propene, we report a >12-σ detection of propadiene and a >17-σ detection of propene at high latitudes inside Jupiter’s auroral region, where the species are most concentrated. For example, at 62 °N (planetocentric) inside Jupiter’s northern auroral region (henceforth ‘NAR’), we derive a 1-mbar propadiene abundance of 2.0 ± 0.2 ppbv, which is 40 ± 3 higher than abundances predicted by the Moses and Poppe (2017) photochemical model (henceforth ‘MP17’), and significantly higher than the 1.2-pbbv upper limit abundance derived at 42 °N (the lowest latitude sampled by the observations). Similarly, we derive a 1-mbar propene abundance 8.1 ± 0.5 ppbv at 62 °N inside Jupiter’s NAR, which is 28 ± 2 higher than the MP17 predicted abundance and significantly higher than the 6-ppbv 1-mbar upper limit abundance derived at 42 °N. The fact that propadiene and propene are most enriched inside Jupiter’s NAR strongly suggests that perturbations to the chemistry by auroral-related heating and exogenous ions/electrons are responsible for their significant enrichment, as has been observed for other unsaturated/aromatic hydrocarbon species. Spectral features of propane (C₃H₈) were not detected at any of the locations sampled by the data (poleward of 42 °N): 3-σ upper limits of ~10 ppbv at 10 mbar were derived at 62 °N inside Jupiter’s NAR, which is ~2.5 times the MP17 predicted abundance. The non-detection of propane could, in part, be explained by the vertical sensitivity of its mid-infrared emission lines to deeper pressures, where there is negligible auroral-related heating to warm the line forming region. The results of this work strongly advocate for development of ion-neutral chemistry models of Jupiter’s polar stratosphere to quantify how strong auroral-related heating and magnetospheric particles modify the reaction pathways that produce higher-order hydrocarbons.

Abstract:

The Lunar Trailblazer mission launched in February of 2025 with the goal of characterizing lunar surface water through a targeted campaign. One instrument on the mission, the Lunar Thermal Mapper (LTM), was tasked with measuring the surface temperature to compare with maps of the form and abundance of water on the lunar surface. LTM's secondary science goals were to identify regolith composition and thermophysical properties as exhibited by mid‐infrared spectral features. Here we show the utility of LTM in distinguishing lunar regolith composition with its 11 narrow bands. Five spectral parameter products were developed to aid in early identification of regions of interest for follow‐on spectral analyses. These products include the Christiansen feature (CF) value, weighted absorption center (WAC) value, WAC band depth, Transparency Roll‐off, and a Diviner CF value equivalent. These products would be used mainly to flag these regions for more detailed follow‐up study with the entire spectral capabilities of the mission instrumentation. The Lunar Thermal Mapper (LTM) is one of two instruments on the Lunar Trailblazer mission launched in February 2025. LTM's primary goal is to provide surface temperature measurements for the lunar surface, in particular for identifying and mapping water on the Moon. LTM is also capable of identifying the compositional and physical properties of different rocks on the surface. Here, we test those capabilities and determine five methods for quickly distinguishing bulk properties of the lunar rocks that can be used by the community to identify regions of interest for further investigation. Mid‐infrared compositional parameters were created and tested for the Lunar Trailblazer mission Spectral parameters can distinguish bulk silicate mineralogy, and identify regions of compositional interest The Christiansen feature roll‐off parameter can provide an initial identification of areas with distinct thermophysical properties Mid‐infrared compositional parameters were created and tested for the Lunar Trailblazer mission Spectral parameters can distinguish bulk silicate mineralogy, and identify regions of compositional interest The Christiansen feature roll‐off parameter can provide an initial identification of areas with distinct thermophysical properties

Abstract:

Abstract The Lunar Thermal Mapper (LTM) instrument is a UK Space Agency funded infrared radiometer designed and built for the National Aeronautics and Space Administration Lunar Trailblazer mission launched in February 2025. LTM is a pushbroom imaging filter radiometer with 15 channels that cover the wavelength range from 6.25 to 100 μm with a 40–70 m/pixel ground sampling. Lunar Trailblazer's mission is to understand the form, abundance and distribution of water across the lunar surface. LTM provides an independent measure of temperature to investigate thermal effects on water's mapped distribution as well as an independent measure of surface mineralogy. The LTM instrument's 15 infrared channels include four broadband temperature sensing channels (6.25–12.5, 12.5–25, 25–50 and 50–100 μm) plus 11 additional narrow band (∼40 cm −1 ) filters from ∼7–10 μm to map and discriminate silicate composition. We review the LTM design and calibration campaign at the University of Oxford's Space Instrumentation facility and show that the instrument has sensitivity from 400 K with a Noise Equivalent Temperature Difference of <0.1 K to <1 K at 110 K for typical integration times (e.g., 30 Hz readout) from a nominal 70–130 km lunar orbit design altitude. Plain Language Summary This paper describes the Lunar Thermal Mapper instrument for NASA's Lunar Trailblazer mission. Lunar Thermal Mapper is a thermal imaging system designed to sense the temperature and composition of the lunar surface using the thermal infrared. By sensing the temperature environment of the Moon, Lunar Thermal Mapper supports the Trailblazer's mission to map water on the lunar surface. Key Points The Lunar Thermal Mapper (LTM) instrument will measure thermal infrared radiation from the Moon across from 400 K to <110 K The LTM instrument completed assembly, testing, calibration and integration on the Lunar Trailblazer spacecraft The LTM instrument demonstrated sensitives of <0.1 K at 400 K and <1 K at 110 K during ground testing and calibration

Abstract:

Hot Jupiters have temperature gradients of several hundreds of degrees between their permanent daysides and nightsides. Such a strong gradient creates winds with speeds of the order of kilometres per second, which advect chemical species over the whole planet. When this transport is faster than the time needed for chemical species to react, it holds back the chemical equilibration of the atmospheric carbon reservoir, which would otherwise transition from CO on the dayside to CH4 on the nightside. Direct evidence of this process has remained elusive so far, as it is often degenerate with other atmospheric processes, such as vertical mixing or non-stellar elemental abundances. Here we present observational evidence for such a fast day-to-night horizontal transport of chemical species by observing the full 18-h orbit of the exoplanet NGTS-10A b with the JWST/NIRSpec instrument. We show that the carbon chemistry is dominated by CO in both the dayside and the nightside of the planet, with a strong depletion of CH4 on the nightside compared with expectations from chemical equilibrium. By measuring the atmospheric abundances of all the main carbon and oxygen molecules, we further demonstrate that the lack of CH4 on the planetary nightside cannot be attributed to non-solar elemental abundances or to vertical mixing mechanisms and must, therefore, be due to fast horizontal transport. Our study shows the fundamental role that atmospheric transport plays in shaping the distribution of chemical species on exoplanet atmospheres.