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Abstract:

Thin-film transmission spectra of ammonium hydrosulfide (NH4SH) ice and ammonia (NH3) ice between 1300 and 12,000 cm-1 were used to determine the ice's optical constants. The films were grown on a sapphire substrate, and a Fourier-transform spectrometer and a grating spectrometer were used together to record the spectra. Lambert's law was used to directly determine the imaginary component of the complex refractive indices; from this, the real component was derived using the Kramers-Kronig algorithm. It is shown that, contrary to what is expected, the optical constants determined for NH3 ice at 80 K are in good agreement with those in the cubic phase, rather than the metastable one. The phase of the NH4SH ice was observed to change from amorphous to polycrystalline as the film was annealed to 160 K. © 2006 Optical Society of America.

Abstract:

In order to enable high quality lens designs using N-BK7, BaLKN3, SF15, and E-SF03 at cryogenic temperatures, we have measured the absolute refractive index of prisms of these four materials using the Cryogenic, High-Accuracy Refraction Measuring System (CHARMS) at NASA's Goddard Space Flight Center, as a function of both wavelength and temperature. For N-BK7, we report absolute refractive index and thermo-optic coefficient (dn/dT) at temperatures ranging from 50 to 300 K at wavelengths from 0.45 to 2.7 mu m; for BaLKN3 we cover temperatures ranging from 40 to 300 K and wavelengths from 0.4 to 2.6 mu m; for SF15 we cover temperatures ranging from 50 to 300 K and wavelengths from 0.45 to 2.6 mu m; for E-SF03 we cover temperatures ranging from 30 to 300 K and wavelengths from 0.45 to 2.8 mu m. We compare our measurements with others in the literature and provide temperature-dependent Sellmeier coefficients based on our data to allow accurate interpolation of index to other wavelengths and temperatures. While we generally find good agreement (+/-2 x 10(-4) for N-BK7, +/-4 x 10(-4) for E-SF03, <1X10(-4) for the other materials) at room temperature between our measured values and those provided by the vendor, there is some variation between the datasheets provided with the prisms we measured and the catalog values published by the vendor. This underlines the importance of measuring the absolute refractive index of the material when precise knowledge of the refractive index is required.