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Abstract:

We examine the time evolution of the entanglement spectrum of a small subsystem of a nonintegrable spin chain following a quench from a product state. We identify signatures in this entanglement spectrum of the distinct dynamical velocities (related to entanglement and operator spreading) that control thermalization. We show that the onset of level repulsion in the entanglement spectrum occurs on different timescales depending on the “entanglement energy”, and that this dependence reflects the shape of the operator front. Level repulsion spreads across the entire entanglement spectrum on a timescale that is parametrically shorter than that for full thermalization of the subsystem. This timescale is also close to when the mutual information between individual spins at the ends of the subsystem reaches its maximum. We provide an analytical understanding of this phenomenon and show supporting numerical data for both random unitary circuits and a microscopic Hamiltonian.

Abstract:

Within a tight-binding approximation, we numerically determine the time evolution of graphene electronic states in the presence of classically vibrating nuclei. There is no reliance on the Born-Oppenheimer approximation within the p-orbital tight-binding basis, although our approximation is "atomically adiabatic": the basis p-orbitals are taken to follow nuclear positions. Our calculations show that the strict adiabatic Born-Oppenheimer approximation fails badly. We find that a diabatic (lazy electrons responding weakly to nuclear distortions) Born-Oppenheimer model provides a much more accurate picture and suggests a generalized many-body Bloch orbital-nuclear basis set for describing electron-phonon interactions in graphene.