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Abstract:

We have realized planar tunnel junctions using both Y123 and Y124 single crystals as base electrodes and Pb as counterelectrode. The crystals, with T c =90 K (Y123) and T c =80 K (Y124), have been chemically etched and natural barriers were formed by a short air exposure. We have compared the tunneling spectra obtained on both systems. The features at about±18mV of the Y123 compound are still observed in the Y124, while the low-bias structures at ±5 mV are not present in the tunneling characteristics of the Y124 system. Linearity of the background conductance is also observed, with less steep slopes in Y124 that might indicate a reduced interlayer coupling in this system. © 1994 Societá Italiana di Fisica.

Abstract:

A cuprate superconductor containing double mercury layers was synthesized with a high-pressure, high-temperature technique. The compound, with chemical formula Hg(2)Ba(2)-Y1-xCaxCu(2)O(8-delta), contains a double HgO layer with structure similar to that of rock salt. The prototype compound Hg(2)Ba(2)YCu(2)O(8-delta) is an insulator. Superconductivity is induced in the system by partially replacing yttrium with calcium.

Abstract:

63Cu(1) NQR signals and their relaxation have been measured in YBa2Cu3O6.1 and ErBa2Cu3O6+x at temperatures between 10 K and 300 K. In YBa2Cu3O6.1 a peak is observed in the spin-lattice relaxation, T1-1, around 140 K. An explanation in terms of doped-hole motion is presented and alternative O(4)-O(5) diffusion mechanisms are critically discussed. In ErBa2Cu3O6+x the low-temparature T1-1 is dominated by magnetic fluctuations of Er; quantitative agreement is found when the correct ground state and magnetic dynamic properties of the rare earth are taken into account. © 1994.