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Abstract:

Abstract We present high-resolution dayside thermal emission observations of the exoplanet WASP-18 b using IGRINS on Gemini South. We remove stellar and telluric signatures using standard algorithms, and we extract the planet signal via cross-correlation with model spectra. We detect the atmosphere of WASP-18 b at a signal-to-noise ratio (S/N) of 5.9 using a full chemistry model, measure H 2 O (S/N = 3.3), CO (S/N = 4.0), and OH (S/N = 4.8) individually, and confirm previous claims of a thermal inversion layer. The three species are confidently detected (>4 σ ) with a Bayesian inference framework, which we also use to retrieve abundance, temperature, and velocity information. For this ultrahot Jupiter (UHJ), thermal dissociation processes likely play an important role. Retrieving abundances constant with altitude and allowing the temperature–pressure profile to adjust freely results in a moderately super-stellar carbon-to-oxygen ratio (C/O = 0.75 − 0.17 + 0.14 ) and metallicity ([M/H] = 1.03 − 1.01 + 0.65 ). Accounting for undetectable oxygen produced by thermal dissociation leads to C/O = 0.45 − 0.10 + 0.08 and [M/H] = 1.17 − 1.01 + 0.66 . A retrieval that assumes radiative–convective–thermochemical equilibrium and naturally accounts for thermal dissociation constrains C/O < 0.34 (2 σ ) and [M/H] = 0.48 − 0.29 + 0.33 , in line with the chemistry of the parent star. Looking at the velocity information, we see a tantalizing signature of different Doppler shifts at the level of a few kilometers per second for different molecules, which might probe dynamics as a function of altitude and/or location on the planet disk. Our results demonstrate that ground-based, high-resolution spectroscopy at infrared wavelengths can provide meaningful constraints on the compositions and climate of highly irradiated planets. This work also elucidates potential pitfalls with commonly employed retrieval assumptions when applied to the spectra of UHJs.

Abstract:

<jats:title>Abstract</jats:title> <jats:p>The gas giant HD 80606 b has a highly eccentric orbit (e ∼ 0.93). The variation due to the rapid shift of stellar irradiation provides a unique opportunity to probe the physical and chemical timescales and to study the interplay between climate dynamics and atmospheric chemistry. In this work, we present integrated models to study the atmospheric responses and the underlying physical and chemical mechanisms of HD 80606 b. We first run three-dimensional general circulation models (GCMs) to establish the atmospheric thermal and dynamical structures for different atmospheric metallicities and internal heat. Based on the GCM output, we then adopted a 1D time-dependent photochemical model to investigate the compositional variation along the eccentric orbit. The transition of the circulation patterns of HD 80606 b matched the dynamics regimes in previous works. Our photochemical models show that efficient vertical mixing leads to deep quench levels of the major carbon and nitrogen species and the quenching behavior does not change throughout the eccentric orbit. Instead, photolysis is the main driver of the time-dependent chemistry. While CH4 dominates over CO through most of the orbits, a transient state of [CO]/[CH4] &amp;gt; 1 after periastron is confirmed for all metallicity and internal heat cases. The upcoming JWST Cycle 1 GO program will be able to track this real-time CH4–CO conversion and infer the chemical timescale. Furthermore, sulfur species initiated by sudden heating and photochemical forcing exhibit both short-term and long-term cycles, opening an interesting avenue for detecting sulfur on exoplanets.</jats:p>

Abstract:

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems. Access to an exoplanet's chemical inventory requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based and high-resolution ground-based facilities. Here we report the medium-resolution (R$\sim$600) transmission spectrum of an exoplanet atmosphere between 3-5 $\mu$m covering multiple absorption features for the Saturn-mass exoplanet WASP-39b, obtained with JWST NIRSpec G395H. Our observations achieve 1.46x photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO$_2$ (28.5$\sigma$) and H$_2$O (21.5$\sigma$), and identify SO$_2$ as the source of absorption at 4.1 $\mu$m (4.8$\sigma$). Best-fit atmospheric models range between 3 and 10x solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO$_2$, underscore the importance of characterising the chemistry in exoplanet atmospheres, and showcase NIRSpec G395H as an excellent mode for time series observations over this critical wavelength range.Comment: 44 pages, 11 figures, 3 tables. Resubmitted after revision to Natur

Abstract:

Even though sub-Neptunes likely represent the most common outcome of planet formation, their natures remain poorly understood. In particular, planets near 1.5-2.5$\,R_\oplus$ often have bulk densities that can be explained equally well with widely different compositions and interior structures, resulting in grossly divergent implications for their formation. Here, we present the full 0.6-5.2$\,\mu \mathrm{m}$ JWST NIRISS/SOSS+NIRSpec/G395H transmission spectrum of the 2.2$\,R_\oplus$ TOI-270d ($4.78\,M_\oplus$, $T_\mathrm{eq}$=350-380 K), delivering unprecedented sensitivity for atmospheric characterization in the sub-Neptune regime. We detect five vibrational bands of CH$_4$ at 1.15, 1.4, 1.7, 2.3, and 3.3$\,\mu$m (9.4$\sigma$), the signature of CO$_2$ at 4.3$\,\mu$m (4.8$\sigma$), water vapor (2.5$\sigma$), and potential signatures of SO$_2$ at 4.0$\,\mu \mathrm{m}$ and CS$_2$ at 4.6$\,\mu\mathrm{m}$. Intriguingly, we find an overall highly metal-rich atmosphere, with a mean molecular weight of $5.47_{-1.14}^{+1.25}$. We infer an atmospheric metal mass fraction of $58_{-12}^{+8}\%$ and a C/O of $0.47_{-0.19}^{+0.16}$, indicating that approximately half the mass of the outer envelope is in high-molecular-weight volatiles (H$_2$O, CH$_4$, CO, CO$_2$) rather than H$_2$/He. We introduce a sub-Neptune classification scheme and identify TOI-270d as a "miscible-envelope sub-Neptune" in which H$_2$/He is well-mixed with the high-molecular-weight volatiles in a miscible supercritical metal-rich envelope. For a fully miscible envelope, we conclude that TOI-270d's interior is $90_{-4}^{+3}\,$wt$\,\%$ rock/iron, indicating that it formed as a rocky planet that accreted a few wt % of H$_2$/He, with the overall envelope metal content explained by magma-ocean/envelope reactions without the need for significant ice accretion. TOI-270d may well be an archetype of the overall population of sub-Neptunes.Comment: 25 pages, 12 figure