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Abstract:

Sulfur chemistry has emerged as an important probe of exoplanet atmospheres in the JWST era, although observational constraints have thus far been largely limited to SO2 and H2S in warm and hot exoplanets. Recent JWST observations have revealed CS2 in several cooler gas giant exoplanets, yielding a new tracer of sulfur chemistry. However, the detailed chemical pathways responsible for the formation of CS2 remain poorly understood. Here, we use TOI-6894 b, a temperate gas giant with evidence for CS2, as a test case for one-dimensional photochemical kinetic-transport modeling and sensitivity analyses of CS2 chemistry. We show that CS2 is produced through coupled thermochemical and photochemical processes involving CH4 and H2S as the primary carbon and sulfur reservoirs, with S2 photolysis driving disequilibrium sulfur chemistry. Our models provide a physically consistent explanation for the observed CS2 feature in TOI-6894 b. Extending our analysis to gas giant exoplanets spanning a wide range of Teq, we find that CS2 abundance peaks in temperate to warm atmospheres (Teq ∼ 500–700 K), and declines toward both lower and higher temperatures. This temperature dependence provides a unified framework for interpreting current CS2 observations, accounting for reported detections in temperate to warm planets and the lack of detections in colder and hotter giant exoplanets. Our results establish CS2 as a complementary probe of sulfur inventories and atmospheric metallicity in cool gas giant exoplanets.

Abstract:

Ultrahot Jupiters (UHJs; Teq ≳ 2000 K) enable simultaneous detection of volatile (ice-forming) and refractory (rock-forming) elements in planetary atmospheres, providing a powerful diagnostic of planet formation and atmospheric processing. We present a comprehensive high-resolution cross-correlation spectroscopy analysis of the UHJ MASCARA-1 b (Teq ≈ 2600 K) using the IGRINS and IGRINS-2 spectrographs. We detect robust (signal-to-noise ratio > 4) signals from H2O, CO, OH, Fe i, Mg i, Ca i, and Ti i, marking the most complete atmospheric inventory of MASCARA-1 b to date. Using a chemically consistent atmospheric inference framework, we constrain elemental abundances to a typical precision of ≈0.2 dex, retrieving a solar atmospheric metallicity ([M/H]⊙ (Formula presented) =0.07−0.13+0.17 ≈1.2 × solar), a C/O ratio (C/O (Formula presented) =0.65−0.08+0.08 ) consistent with solar value (C/O = 0.59), an enhanced refractory abundance ([ (Formula presented) R /H]⊙= (Formula presented) 0.40−0.17+0.23≈2.5× solar; ≈3.8 × stellar), and a moderately supersolar refractory-to-volatile ratio ([ (Formula presented) R/V ]⊙ =  (Formula presented) 0.36−0.09+0.11 ≈ 2.3× solar). Comparison with formation models suggests that MASCARA-1 b most likely accreted material between the soot–H2O or H2O–CO snowlines (at 68% confidence). We additionally find stellar values for atmospheric Ti/Fe and Ca/Fe ratios (at 68% confidence). The Mg/Fe is also found to be consistent with stellar value at 95% confidence. Therefore, we do not find strong indication of nightside cold trapping in MASCARA-1 b. As homogeneous refractory-to-volatile measurements expand across the UHJ population, particularly with upcoming Extremely Large Telescopes, these diagnostics will enable statistically robust tests of emerging trends in giant planet formation and atmospheric evolution.

Abstract:

Discovered deep within the “Neptunian desert,” LTT9779b remains the only known ultrahot Neptune, prompting significant speculation regarding its unique formation and evolutionary history. Its exceptionally high geometric albedo has previously been attributed either to the presence of clouds or to an extremely metal-rich atmosphere. Here, we present a comprehensive panchromatic analysis of its dayside atmosphere using JWST NIRISS and NIRSpec/G395H observations to characterize its atmospheric structure and composition. Leveraging the exceptional signal-to-noise ratio (SNR) in the observed spectra, we report a 3σ-to-5σ detection of dayside clouds, with strong evidence for Mg2SiO4(s) (silicate) condensation. This constitutes the first statistically significant detection of clouds on the dayside of a Neptunian-mass exoplanet. We demonstrate that a highly reflective cloud deck, rather than an extremely high-metallicity atmosphere, is the most likely explanation for the planet’s anomalously high optical albedo. Furthermore, our atmospheric retrievals yield robust detections of both CO (∼4.88σ) and CO2 (∼8.76σ), while providing tentative constraints on the H2O abundance and upper limits on SiO, TiO, and VO. Finally, our analysis places a robust constraint on the C/O ratio of 0.984 ± 0.019. This aligns LTT9779b with other known ultrahot Jupiters exhibiting supersolar C/O ratios, suggesting a broader trend driven by the sequestration of oxygen-bearing condensates in ultrahot atmospheres.

Abstract:

Ultra-hot Jupiters (UHJs) present extreme atmospheric phenomena not found in the solar system. These planets’ daysides experience strong temperature inversions, molecular species (including H2) dissociate, and magnetism effects disrupt atmospheric circulation. On their nightsides, H2 can recombine and clouds may form. Spectroscopic phase curves allow us to measure these spatially inhomogeneous conditions, which can then be interpreted with three-dimensional (3D) models. In this work, we compare the JWST Near Infrared Imager and Slitless Spectrograph (or NIRISS) spectroscopic phase curve of the UHJ WASP-121 b to state-of-the-art 3D models with varying modeling assumptions, including the aforementioned physical phenomena. We demonstrate the importance of accurately accounting for the planet’s radius when comparing data and models, as it changes the implied overall planetary emission. We find that the 3D models predict planetary emission that is ∼12% higher than observed, contributing to the continued tension between measured and predicted hot Jupiter albedos. We identify multiple lines of evidence confirming a strong source of drag operating in this planet’s atmosphere. In addition, the nightside emission spectrum is devoid of strong absorption features, which may be best explained by nightside clouds. One feature of the dataset that is not reproduced by the 3D models is a trend toward increasingly eastward phase offsets at wavelengths shorter than ∼1.4 μm. This result is inconsistent with reflection from dayside clouds, nor can it be explained by removing atmospheric opacity sources. Our analysis highlights the complexities involved in generating 3D models and interpreting observations of UHJs in the JWST era.

Abstract:

Ultrahot Jupiters (UHJs) are exceptional laboratories for studying planetary atmospheres under extreme irradiation conditions. With close-in tidally locked orbits, these planets can have daysides hot enough for metals to be significantly ionized while still maintaining nightsides cold enough for refractory species to potentially condense. We present an analysis of the UHJ HAT-P-70b taken with the MAROON-X high-resolution spectrograph. Using cross correlations, we detect 14 neutral and singly ionized species, including Fe I, Fe II, Ti I, Ca I, Ca II, Cr I, Na I, V I, Mn I, Ni I, Mg I, Ba II, O I, and Sr I, with tentative evidence for H I, Co I, and K I. The absorption signals exhibit blueshifts on the order of a few kilometers per second, consistent with day-to-night winds. We further constrain relative abundances with atmospheric retrievals and demonstrate that some inferred elemental abundance ratios depend strongly on modeling assumptions. In particular, we show that a well-mixed retrieval approach neglecting ionization can strongly bias highly ionizable elements such as Ca and Ti. Accounting for the effects of equilibrium chemistry and thermal ionization generally results in inferred elemental abundance ratios that are closer to expectations for a solar-like composition, although not in all cases. Interestingly, we find a distinct nickel enrichment on HAT-P-70b, adding to the growing number of UHJ studies where the Ni abundance is seemingly enhanced. Our results underline the importance of considering physical and chemical atmospheric processes such as ionization when interpreting high-resolution transmission spectra of UHJs.