51ÁÔÆæÈë¿Ú

Abstract:

A clear understanding of the interactions between the building blocks of self-assembled molecular materials is essential for rational design of functional nanostructures. Intermolecular interactions have been investigated for three different classes of fullerenes in single-walled carbon nanotubes (SWNTs); van der Waals molecule -molecule and molecule-SWNT interactions control the geometry of the molecular arrays inside nanotubes; electrostatic intermolecular forces influence the alignment of polar endohedral fullerenes M@C-82; and hydrogen bonding between functionalised fullerenes has a significant effect on the selectivity of insertion of functionalised fullerenes into SWNTs.

Abstract:

Miniband charge transport was investigated by Monte Carlo simulations of electronic motion in short period superlattices of type-II energy band alignment (InAs/GaSb composition). The strong decrease of the miniband energy width when the electronic in-plane energy increases, characteristic of type-II superlattices, leads to a conductivity that is very sensitive to a magnetic field applied parallel to the axis of the superlattice. For structures with a miniband energy width greater than the optic phonon energy, the differential conductance can be changed from positive to negative by the magnetic field, due to the suppression of optic phonon emission.

Abstract:

The first FIRM-PL measurements in InSb/GaSb quantum dots have been performed. At low power densities the FIR absorption causes a transfer of carriers between dots and effectively cools the system, preferentially populating large, low energy dots and increasing the photoluminescence (PL) intensity, At higher powers the carrier temperature increases and the PL intensity falls. The spectral dependence of the FIRM-PL signal measures the energy spectrum of the quantum dots, showing a peak at 14.5 meV corresponding to transitions between the first two energy levels of the quantum dot distribution. (C) 2003 Elsevier B.V. All rights reserved.