Formation of a meltable purinate metal鈥搊rganic framework and its glass analogue
Chemical Communications Royal Society of Chemistry 59:6 (2022) 732-735
Abstract:
The chemistries that can be incorporated within melt-quenched zeolitic imidazolate framework (ZIF) glasses are currently limited. Here we describe the preparation of a previously unknown purine-containing ZIF which we name ZIF-UC-7. We find that it melts and forms a glass at one of the lowest temperatures reported for 3D hybrid frameworks.Mapping short-range order at the nanoscale in metal鈥搊rganic framework and inorganic glass composites
Nanoscale Royal Society of Chemistry 14:44 (2022) 16524-16535
Abstract:
) inorganic glass. STEM-ePDF enables separation of MOF and inorganic glass domains from atomic structure differences alone, showing abrupt changes in atomic structure at interfaces with interatomic correlation distances seen in X-ray PDF preserved at the nanoscale. These findings underline that the average bulk amorphous structure is retained at the nanoscale in the growing family of MOF glasses and composites, a previously untested assumption in PDF analyses crucial for future non-crystalline nanostructure engineering.Formation of new crystalline qtz-[Zn(mIm)2] polymorph from amorphous ZIF-8
Chemical Communications Royal Society of Chemistry 58:85 (2022) 11949-11952
Abstract:
gas sorption properties and dye adsorption ability were investigated.Modeling the Effect of Defects and Disorder in Amorphous Metal鈥揙rganic Frameworks
Chemistry of Materials American Chemical Society (ACS) 34:20 (2022) 9042-9054
Semi鈥恆nalytic theory of multiphonon effects on the static structure factors of warm solids
Acta Crystallographica Section A: Foundations and advances International Union of Crystallography (IUCr) 78:5 (2022) 415-421