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Abstract:

Resonant magnetic x-ray scattering has been used to investigate the magnetic structure of the magnetoelectric multiferroic DyMn 2O 5. We have studied the magnetic structure in the ferroelectric phase of this material, which displays the strongest ferroelectric polarization and magnetodielectric effect of the RMn 2O 5 (where R is a rare-earth ion, Y or Bi) family. The magnetic structure observed is similar to that of the other members of the series, but differs in the direction of the ordered moments. In DyMn 2O 5, both the Dy and Mn moments lie close to the b axis, whereas in other RMn 2O 5 they lie close to the a axis. © 2012 American Physical Society.

Abstract:

The magneto-electric multiferroic TbMn 2O 5 has a complex magnetic structure in three different magnetically ordered phases. We have determined the nature of the induced magnetic order on the oxygen sites in the commensurate magnetic phase through full linear X-ray polarisation analysis at the oxygen K edge. This has been achieved rotating the linear polarisation of the incident beam at the source, and using multilayers to analyse the polarisation state of the scattered X-ray beam. We have confirmed that the anisotropy of the magnetic scattering at the oxygen edge is consistent with the anisotropy of the manganese magnetic structure. © 2012 EDP Sciences, Springer-Verlag.

Abstract:

Through powder x-ray diffraction we have investigated the structural behavior of SmVO 3, in which orbital and magnetic degrees of freedom are believed to be closely coupled to the crystal lattice. We have found, contrary to previous reports, that SmVO 3 exists in a single, monoclinic phase below 200 K. The associated crystallographic distortion is then stabilized through the magnetostriction that occurs below 134 K. The crystal structure has been refined using synchrotron x-ray powder diffraction data measured throughout the structural phase diagram, showing a substantial Jahn-Teller distortion of the VO 6 octahedra in the monoclinic phase, compatible with the expected G-type orbital order. Changes in the vanadium ion crystal field due to the structural and magnetic transitions have then been probed by resonant x-ray diffraction. © 2012 American Physical Society.

Abstract:

We report on a detailed x-ray resonant scattering study of the bilayer iridate compound Sr 3Ir 2O 7 at the Ir L 2 and L 3 edges. Resonant scattering at the Ir L 3 edge has been used to determine that Sr 3Ir 2O 7 is a long-range ordered antiferromagnet below T N 230K with an ordering wave vector q=(12,12,0). The energy resonance at the L 3 edge was found to be a factor of ∼30 times larger than that at the L 2 edge. This remarkable effect has been seen in the single-layer compound Sr 2IrO 4 and has been linked to the observation of a J eff=12 spin-orbit insulator. Our result shows that despite the modified electronic structure of the bilayer compound, caused by the larger bandwidth, the effect of strong spin-orbit coupling on the resonant magnetic scattering persists. Using the program sarah, we have determined that the magnetic order consists of two domains with propagation vectors k 1=(12,12,0) and k 2=(12,-12,0), respectively. A raster measurement of a focused x-ray beam across the surface of the sample yielded images of domains of the order of 100μm, with odd and even L components, respectively. Fully relativistic, monoelectronic calculations using the Green's function technique for a muffin-tin potential have been employed to calculate the relative intensities of the L 2,3 edge resonances, comparing the effects of including spin-orbit coupling and the Hubbard U term. A large L 3 to L 2 edge intensity ratio (∼5) was found for calculations including spin-orbit coupling. Adding the Hubbard U term had no significant effect on the calculated spectra. © 2012 American Physical Society.